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Technology
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Topic:

Lithium Rechargeable Batteries (Research Paper Sample)

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This research was on the different types of batteries in the market and their advantages.

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Content:

Lithium Rechargeable Batteries
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Instutution:
Abstract
In this term paper, a discussion on how lithium batteries work will be tabled and the conclusion will be made on how they work. However, not only the functions of the lithium batteries will be discussed but also what components and materials are used to make them work as required.
Introduction
Before talking about what a lithium battery is and how it works, we will first have to know what a battery is for us to be able to understand it better. In a brief way, the battery can be said to be an electric device which has electrochemical cells that are used to transform stored chemical energy into electrical energy. The cells contain both positive and negative terminals which allow the movement of ions and therefore enhancing the flow of current in the cell. There are two types of cells, which can be categorized as primary and secondary. These batteries have different features, but their functions are the same. For a primary cell a user has to use them only once then dispose them after they are exhausted, one of the best examples of this batteries are the alkaline batteries used in watches and torches. While, on the other hand, secondary batteries do not have to be disposed after use since they can be recharged more than one time when they exhaust power. A good example of this kind of cell is the acid battery which is used in vehicles and also most of the lithium batteries we find on portable electronic devices.
When many people hear the word batteries they only imagine of a small object used to power small devices not knowing that batteries can be of different sizes depending on what they are supposed to power. This can be elaborated further by different batteries such as the mini batteries we see in wristwatches; these are familiar to many people and can be said to be the smallest types of cells while on the other hand we have power banks which are rechargeable batteries used in large institution for power backup in case of a power shortage and this can be as large as a room to be specific. When comparing batteries to other forms of power we can say that, batteries tend to have a lower energy specification since they have to do all conversions and deliver their energy in the form of electricity.
When we talk about lithium batteries, it refers to disposable batteries that can also be said to be primary batteries that have lithium metal as an anode. When looking at the specifics of lithium batteries we can say that the cells are meant to produce low power voltages of about 1.5V to 3.7V and this all depends on the designs and also the types of compounds used to manufacture the lithium battery. However, lithium batteries can be said to be different from another kind of cells due to their capability to stay with power for long periods of time. When comparing lithium batteries to lithium-ion batteries which are rechargeable, we can say that for lithium-ion batteries the ions are designed to move from the cathode to anode by the use of reversible insertion of ions into a compound unlike in lithium batteries which use metallic lithium.
Theory
Lithium batteries can be said to have been invented by M. Whittingham back in 1970. However according to Whittingham he used titanium sulfide mixed with lithium as the electric conductors. However, batteries that used lithium as a reactor were supposed to be dangerous. This because metallic lithium is a very high reactor and safety measures had to be taken while working with metallic lithium, and by this, the team that was under research proposed that they be using lithium instead of metallic lithium. There are three major components that are functional in a Li-ion battery these are the cathode, the anode and the electrolytes. The anode side of a lithium-ion battery consists of carbon. On the other side, the cathode is a metal oxide while the electrolyte is composed of lithium salt in an organic solution that can dissolve. Electrodes come in many forms depending on if they are negative or positive, one of the mostly used negative electrode is graphite, while on the positive side electrodes can be in three different materials i.e.: spinel, polyanion and last is layered oxide. Electrolytes are a mixture of several materials such as organic carbonates or ethylene carbonate. Since electrolytes do not contain water elements they are forced to use anion salts such as hexafluorophosphate, lithium and many others since it all depends on the materials you like. From the look of things we can say lithium batteries are more expensive but on the brighter side they can be functional over wide temperature ranges and also have high energy density, however, they should always have a protective circuit which hinders the battery from exploding or discharging high energy since it limits its voltage maximum power.
For portable electronic devices such as a laptop or iPad, they are fitted in with lithium-ion battery which comes with temperature sensors which are used to regulate the amount of energy to be taken in by the machine and also stop it from overheating when charging.
Lithium-ion batteries which can also be referred to as Li-ion batteries can be categorized in the rechargeable family, whereby lithium ions in the battery have to move negative to positive electrodes when the battery is discharging stored energy and vice versa when charging the battery. Unlike lithium batteries that use metallic lithium, Li-ion are designed to use intercalated form of lithium. The consistency of lithium-ion batteries plays a big role in the movement of ions through the help of electrolytes. This kind of batteries are mostly found on portable electronics and can be said to be the most common type of rechargeable batteries for most kinds of electronics, they can be said to have a low energy loss system when not being used and they also have a high energy storage capacity as compared to their small sizes and also they have no short term energy loss and this means even if you switch the electronic device off by the time you turn it on the amount of energy stored will still be the same. However, lithium-ion batteries are slowly taking over the market and expanding their use and capabilities. They are also being used in military for powering some of their electronic machineries and cars and also on some aerospace equipment. As technology advances, most companies are also looking forward to replacing the use of lead acid batteries with lithium-ion ones when manufacturing vehicles and all other machines that use lead-acid batteries as a source of power, the point in this is just coming up with a lithium-ion which is smaller in size and can be able to sustain the same amount of energy as the lead acid batteries.
For lithium-ion batteries to charge or discharge energy, there are several stages that they have to go through first. When the lithium-ion battery charges there must be a presence of an external electrical power source or basically a charger which should supply the battery with enough amount of voltage which should be higher than the amount of voltage produced by the battery and there causing the energy being produced by the battery flow backwards as opposed by the charger. Through charging the lithium-ion battery, the ions in the battery are forced to flow from the cathode to anode and eventually become firmly fixed to the porous electrode object. On the other hand, during discharge of energy in a lithium-ion battery, the flow of current is triggered by lithium-ions, which direct the current from anode to cathode through a solution which its water of crystallization has been removed.
When charging a single Li-ion battery and a complete Li-ion battery the processes taken during the charging are a bit different. When it comes to a single Li-ion battery, there are two steps that take place while charging, these are the constant current and voltage source. On the other hand, a complete Li-ion battery is charged through three processes that are, constant current, balance which is not needed when the battery is balanced and finally voltage source. In these processes one can say that during a constant current phase, the charger discharges a constant current which is supplied to the battery in an equally raising voltage, until the voltage limit supposed to be applied in a single cell is reached. However, when charging the battery the charger will reduce the charging power when it reaches the balanced phase, and after doing this the state of all cells is taken to the same level to each other by a balancing circuit to such a point that all the battery gets to the same level and becomes balanced. On the constant voltage stage, when charging the charger uses a voltage that is the same as the maximum cell voltage multiplied to the number of cells in the battery, this is because current reduces as it goes down to zero until the current is under the minimum set amount. When charging a lithium-ion battery it is always advisable to check its voltage limits since charging it with a charger which has more power voltage than the battery might cause and explosion or damage of both the battery and the charger.
On lithium-ion batteries charging can also be affected by temperature and other factors. However, the batteries do not have restrictions on when and where to use, and this is an advantage they come with since you can use them under all kinds of temperatures. The only problem is that they are affected by temperatures when it comes to charging, when you charge the batteries in places with high temperatures it can affect the battery causing it to have a short life span or even spoil it completely. Therefore, it is always advisable that you charge the battery in a room with low or cold temperatures like 4 to 38 °C. At lower temperatures below 4 °C charging is also inevitable but it is always advisable that you cha...
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